Is there a way to get bigger breast without taking pills?
Answers: no
and pills don't work either
you can get a boob job but that's about it
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There is an ebook that I'm familiar with that discusses a number of breast enhancement exercises and supplements that you can try to use at home instead of having to take pills.
There's also a cream which has been shown to be pretty effective too that you simply massage into the breasts and it stimulates the breast tissue to increase in size.
There's more info on both these products at the site below.